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In Situ Study of Catalytic Processes: Neutron Diffraction of a Methanol Synthesis Catalyst at Industrially Relevant Pressure

Identifieur interne : 004A32 ( Main/Exploration ); précédent : 004A31; suivant : 004A33

In Situ Study of Catalytic Processes: Neutron Diffraction of a Methanol Synthesis Catalyst at Industrially Relevant Pressure

Auteurs : Timur Kandemir [Allemagne] ; Frank Girgsdies [Allemagne] ; Thomas C. Hansen [France] ; Klaus-Dieter Liss [Australie] ; Igor Kasatkin [Allemagne] ; Edward L. Kunkes [Allemagne] ; Gregor Wowsnick [Allemagne] ; Nikolas Jacobsen [Allemagne] ; Robert Schlögl [Allemagne] ; Malte Behrens [Allemagne]

Source :

RBID : ISTEX:5329AFCC9597EC39DACFC574C9BD6C15F7512670

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English descriptors

Abstract

Studying the workplace: An industrial methanol synthesis catalyst operating at high pressure was studied by in situ neutron diffraction. The peculiar microstructure of Cu/ZnO/Al2O3 nanocatalysts was found to be stable under reaction conditions. Stacking fault annealing and brass formation was only observed at temperatures higher than used in the methanol synthesis process, providing support for active role of defects in this catalyst system.

Url:
DOI: 10.1002/anie.201209539


Affiliations:


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Le document en format XML

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<div type="abstract">Studying the workplace: An industrial methanol synthesis catalyst operating at high pressure was studied by in situ neutron diffraction. The peculiar microstructure of Cu/ZnO/Al2O3 nanocatalysts was found to be stable under reaction conditions. Stacking fault annealing and brass formation was only observed at temperatures higher than used in the methanol synthesis process, providing support for active role of defects in this catalyst system.</div>
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